C C Ground state configurations and ionization energies of free atoms of C the elements Z=1-99. C C Ionization energies are from T.A. Carlson, 'Photoelectron and Auger C Spectroscopy' (Plenum Press, New York and London, 1975). C C The last column gives the one-electron Compton profiles at P_z=0, in C atomic units. Taken from F. Biggs, L. B. Mendelsohn and J. B. Mann, C At. Data and Nucl. Data Tables 16 (1975) 201-309. C C C +--- Atomic number (Z). C | +--- Code number of the shell. C | | +--- Shell (nlj). C | | | +--- Shell occupation number (f_i). C | | | | (negative values: lowest chemical valences) C | | | | +--- Ionization energy (eV). C | | | | | +-- One-electron Compton profile at P_z=0. C | | | | | | C | | | | | | C V V V V V V 1 1 1s1/2 1 1.36000E+01 8.49E-01 2 1 1s1/2 2 2.45900E+01 5.35E-01 3 1 1s1/2 2 5.80000E+01 3.29E-01 3 2 2s1/2 -1 5.39200E+00 1.94E+00 4 1 1s1/2 2 1.15000E+02 2.37E-01 4 2 2s1/2 -2 9.32200E+00 1.34E+00 5 1 1s1/2 2 1.92000E+02 1.86E-01 5 2 2s1/2 -2 1.13860E+01 1.00E+00 5 3 2p1/2 -1 1.13860E+01 6.15E-01 6 1 1s1/2 2 2.88000E+02 1.53E-01 6 2 2s1/2 2 1.65900E+01 8.04E-01 6 3 2p1/2 -2 1.12600E+01 4.88E-01 7 1 1s1/2 2 4.03000E+02 1.30E-01 7 2 2s1/2 2 2.03300E+01 6.72E-01 7 3 2p1/2 2 1.45300E+01 4.07E-01 7 4 2p3/2 1 1.45300E+01 4.07E-01 8 1 1s1/2 2 5.38000E+02 1.13E-01 8 2 2s1/2 2 2.84800E+01 5.79E-01 8 3 2p1/2 2 1.36200E+01 3.50E-01 8 4 2p3/2 2 1.36200E+01 3.50E-01 9 1 1s1/2 2 6.94000E+02 1.00E-01 9 2 2s1/2 2 3.78500E+01 5.08E-01 9 3 2p1/2 2 1.74200E+01 3.07E-01 9 4 2p3/2 3 1.74200E+01 3.07E-01 10 1 1s1/2 2 8.70100E+02 9.00E-02 10 2 2s1/2 2 4.84700E+01 4.53E-01 10 3 2p1/2 2 2.16600E+01 2.74E-01 10 4 2p3/2 4 2.15600E+01 2.74E-01 11 1 1s1/2 2 1.07500E+03 8.15E-02 11 2 2s1/2 2 6.60000E+01 3.90E-01 11 3 2p1/2 2 3.40000E+01 2.25E-01 11 4 2p3/2 4 3.40000E+01 2.25E-01 11 5 3s1/2 -1 5.13900E+00 2.07E+00 12 1 1s1/2 2 1.30800E+03 7.45E-02 12 2 2s1/2 2 9.20000E+01 3.42E-01 12 3 2p1/2 2 5.40000E+01 1.92E-01 12 4 2p3/2 4 5.40000E+01 1.92E-01 12 5 3s1/2 -2 7.64600E+00 1.59E+00 13 1 1s1/2 2 1.56400E+03 6.86E-02 13 2 2s1/2 2 1.21000E+02 3.05E-01 13 3 2p1/2 2 7.70000E+01 1.68E-01 13 4 2p3/2 4 7.70000E+01 1.68E-01 13 5 3s1/2 -2 9.07500E+00 1.24E+00 13 6 3p1/2 -1 9.07500E+00 9.19E-01 14 1 1s1/2 2 1.84400E+03 6.35E-02 14 2 2s1/2 2 1.54000E+02 2.75E-01 14 3 2p1/2 2 1.04000E+02 1.49E-01 14 4 2p3/2 4 1.04000E+02 1.49E-01 14 5 3s1/2 2 1.34600E+01 1.04E+00 14 6 3p1/2 -2 8.15100E+00 7.44E-01 15 1 1s1/2 2 2.14800E+03 5.92E-02 15 2 2s1/2 2 1.91000E+02 2.51E-01 15 3 2p1/2 2 1.35000E+02 1.34E-01 15 4 2p3/2 4 1.34000E+02 1.34E-01 15 5 3s1/2 2 1.61500E+01 8.97E-01 15 6 3p1/2 -2 1.04900E+01 6.31E-01 15 7 3p3/2 -1 1.04900E+01 6.31E-01 16 1 1s1/2 2 2.47600E+03 5.53E-02 16 2 2s1/2 2 2.32000E+02 2.30E-01 16 3 2p1/2 2 1.70000E+02 1.22E-01 16 4 2p3/2 4 1.68000E+02 1.22E-01 16 5 3s1/2 2 2.02000E+01 7.94E-01 16 6 3p1/2 -2 1.03600E+01 5.51E-01 16 7 3p3/2 -2 1.03600E+01 5.51E-01 17 1 1s1/2 2 2.82900E+03 5.20E-02 17 2 2s1/2 2 2.77000E+02 2.13E-01 17 3 2p1/2 2 2.08000E+02 1.12E-01 17 4 2p3/2 4 2.06000E+02 1.12E-01 17 5 3s1/2 2 2.45400E+01 7.13E-01 17 6 3p1/2 2 1.29700E+01 4.90E-01 17 7 3p3/2 3 1.29700E+01 4.90E-01 18 1 1s1/2 2 3.20630E+03 4.90E-02 18 2 2s1/2 2 3.26500E+02 1.98E-01 18 3 2p1/2 2 2.50600E+02 1.04E-01 18 4 2p3/2 4 2.48500E+02 1.04E-01 18 5 3s1/2 2 2.92400E+01 6.49E-01 18 6 3p1/2 2 1.59400E+01 4.42E-01 18 7 3p3/2 4 1.57600E+01 4.42E-01 19 1 1s1/2 2 3.61000E+03 4.64E-02 19 2 2s1/2 2 3.81000E+02 1.85E-01 19 3 2p1/2 2 2.99000E+02 9.65E-02 19 4 2p3/2 4 2.96000E+02 9.65E-02 19 5 3s1/2 2 3.70000E+01 5.70E-01 19 6 3p1/2 2 1.90000E+01 3.76E-01 19 7 3p3/2 4 1.87000E+01 3.76E-01 19 10 4s1/2 -1 4.34100E+00 2.46E+00 20 1 1s1/2 2 4.04100E+03 4.40E-02 20 2 2s1/2 2 4.41000E+02 1.74E-01 20 3 2p1/2 2 3.53000E+02 9.02E-02 20 4 2p3/2 4 3.49000E+02 9.02E-02 20 5 3s1/2 2 4.60000E+01 5.08E-01 20 6 3p1/2 2 2.80000E+01 3.30E-01 20 7 3p3/2 4 2.80000E+01 3.30E-01 20 10 4s1/2 -2 6.11300E+00 1.95E+00 21 1 1s1/2 2 4.49400E+03 4.18E-02 21 2 2s1/2 2 5.03000E+02 1.64E-01 21 3 2p1/2 2 4.08000E+02 8.47E-02 21 4 2p3/2 4 4.03000E+02 8.47E-02 21 5 3s1/2 2 5.50000E+01 4.71E-01 21 6 3p1/2 2 3.30000E+01 3.04E-01 21 7 3p3/2 4 3.30000E+01 3.04E-01 21 8 3d3/2 -1 7.02700E+00 3.10E-01 21 10 4s1/2 -2 7.02700E+00 1.84E+00 22 1 1s1/2 2 4.97000E+03 3.99E-02 22 2 2s1/2 2 5.67000E+02 1.55E-01 22 3 2p1/2 2 4.65000E+02 7.98E-02 22 4 2p3/2 4 4.59000E+02 7.98E-02 22 5 3s1/2 2 6.40000E+01 4.41E-01 22 6 3p1/2 2 3.90000E+01 2.82E-01 22 7 3p3/2 4 3.80000E+01 2.82E-01 22 8 3d3/2 2 8.00000E+00 2.75E-01 22 10 4s1/2 -2 6.82000E+00 1.76E+00 23 1 1s1/2 2 5.47000E+03 3.81E-02 23 2 2s1/2 2 6.33000E+02 1.47E-01 23 3 2p1/2 2 5.25000E+02 7.55E-02 23 4 2p3/2 4 5.18000E+02 7.55E-02 23 5 3s1/2 2 7.20000E+01 4.15E-01 23 6 3p1/2 2 4.40000E+01 2.64E-01 23 7 3p3/2 4 4.30000E+01 2.64E-01 23 8 3d3/2 3 8.00000E+00 2.50E-01 23 10 4s1/2 -2 6.74000E+00 1.69E+00 24 1 1s1/2 2 5.99500E+03 3.65E-02 24 2 2s1/2 2 7.02000E+02 1.40E-01 24 3 2p1/2 2 5.89000E+02 7.16E-02 24 4 2p3/2 4 5.80000E+02 7.16E-02 24 5 3s1/2 2 8.00000E+01 3.98E-01 24 6 3p1/2 2 4.90000E+01 2.53E-01 24 7 3p3/2 4 4.80000E+01 2.53E-01 24 8 3d3/2 4 8.25000E+00 2.61E-01 24 9 3d5/2 -1 7.50800E+00 2.61E-01 24 10 4s1/2 -1 7.50800E+00 1.85E+00 25 1 1s1/2 2 6.54400E+03 3.50E-02 25 2 2s1/2 2 7.55000E+02 1.33E-01 25 3 2p1/2 2 6.56000E+02 6.81E-02 25 4 2p3/2 4 6.45000E+02 6.81E-02 25 5 3s1/2 2 8.90000E+01 3.73E-01 25 6 3p1/2 2 5.50000E+01 2.35E-01 25 7 3p3/2 4 5.30000E+01 2.35E-01 25 8 3d3/2 4 9.00000E+00 2.15E-01 25 9 3d5/2 1 9.00000E+00 2.15E-01 25 10 4s1/2 -2 7.43400E+00 1.59E+00 26 1 1s1/2 2 7.11700E+03 3.36E-02 26 2 2s1/2 2 8.51000E+02 1.27E-01 26 3 2p1/2 2 7.26000E+02 6.50E-02 26 4 2p3/2 4 7.13000E+02 6.50E-02 26 5 3s1/2 2 9.80000E+01 3.55E-01 26 6 3p1/2 2 6.10000E+01 2.23E-01 26 7 3p3/2 4 5.90000E+01 2.23E-01 26 8 3d3/2 4 9.00000E+00 2.01E-01 26 9 3d5/2 2 9.00000E+00 2.01E-01 26 10 4s1/2 -2 7.87000E+00 1.55E+00 27 1 1s1/2 2 7.71500E+03 3.23E-02 27 2 2s1/2 2 9.31000E+02 1.22E-01 27 3 2p1/2 2 8.00000E+02 6.21E-02 27 4 2p3/2 4 7.85000E+02 6.21E-02 27 5 3s1/2 2 1.07000E+02 3.39E-01 27 6 3p1/2 2 6.80000E+01 2.12E-01 27 7 3p3/2 4 6.60000E+01 2.12E-01 27 8 3d3/2 4 9.00000E+00 1.90E-01 27 9 3d5/2 3 9.00000E+00 1.90E-01 27 10 4s1/2 -2 7.86400E+00 1.51E+00 28 1 1s1/2 2 8.33800E+03 3.11E-02 28 2 2s1/2 2 1.01500E+03 1.17E-01 28 3 2p1/2 2 8.77000E+02 5.95E-02 28 4 2p3/2 4 8.60000E+02 5.95E-02 28 5 3s1/2 2 1.17000E+02 3.25E-01 28 6 3p1/2 2 7.50000E+01 2.02E-01 28 7 3p3/2 4 7.30000E+01 2.02E-01 28 8 3d3/2 4 1.00000E+01 1.79E-01 28 9 3d5/2 4 1.00000E+01 1.79E-01 28 10 4s1/2 -2 7.63500E+00 1.47E+00 29 1 1s1/2 2 8.98600E+03 3.01E-02 29 2 2s1/2 2 1.10300E+03 1.12E-01 29 3 2p1/2 2 9.58000E+02 5.71E-02 29 4 2p3/2 4 9.38000E+02 5.71E-02 29 5 3s1/2 2 1.27000E+02 3.15E-01 29 6 3p1/2 2 8.20000E+01 1.96E-01 29 7 3p3/2 4 8.00000E+01 1.96E-01 29 8 3d3/2 4 1.10000E+01 1.85E-01 29 9 3d5/2 6 1.04000E+01 1.85E-01 29 10 4s1/2 -1 7.72600E+00 1.64E+00 30 1 1s1/2 2 9.66300E+03 2.90E-02 30 2 2s1/2 2 1.19800E+03 1.08E-01 30 3 2p1/2 2 1.04700E+03 5.49E-02 30 4 2p3/2 4 1.02400E+03 5.49E-02 30 5 3s1/2 2 1.41000E+02 2.99E-01 30 6 3p1/2 2 9.40000E+01 1.86E-01 30 7 3p3/2 4 9.10000E+01 1.86E-01 30 8 3d3/2 4 1.20000E+01 1.62E-01 30 9 3d5/2 6 1.12000E+01 1.62E-01 30 10 4s1/2 -2 9.39400E+00 1.41E+00 31 1 1s1/2 2 1.03710E+04 2.81E-02 31 2 2s1/2 2 1.30200E+03 1.04E-01 31 3 2p1/2 2 1.14600E+03 5.28E-02 31 4 2p3/2 4 1.11900E+03 5.28E-02 31 5 3s1/2 2 1.62000E+02 2.85E-01 31 6 3p1/2 2 1.11000E+02 1.76E-01 31 7 3p3/2 4 1.07000E+02 1.76E-01 31 8 3d3/2 4 2.10000E+01 1.46E-01 31 9 3d5/2 6 2.00000E+01 1.46E-01 31 10 4s1/2 -2 9.33300E+00 1.18E+00 31 11 4p1/2 -1 9.33300E+00 9.15E-01 32 1 1s1/2 2 1.11070E+04 2.72E-02 32 2 2s1/2 2 1.41300E+03 1.01E-01 32 3 2p1/2 2 1.25100E+03 5.09E-02 32 4 2p3/2 4 1.22000E+03 5.09E-02 32 5 3s1/2 2 1.84000E+02 2.71E-01 32 6 3p1/2 2 1.30000E+02 1.67E-01 32 7 3p3/2 4 1.25000E+02 1.67E-01 32 8 3d3/2 4 3.30000E+01 1.33E-01 32 9 3d5/2 6 3.20000E+01 1.33E-01 32 10 4s1/2 2 1.43000E+01 1.03E+00 32 11 4p1/2 -2 7.90000E+00 7.69E-01 33 1 1s1/2 2 1.18710E+04 2.63E-02 33 2 2s1/2 2 1.53100E+03 9.71E-02 33 3 2p1/2 2 1.36200E+03 4.91E-02 33 4 2p3/2 4 1.32700E+03 4.91E-02 33 5 3s1/2 2 2.08000E+02 2.58E-01 33 6 3p1/2 2 1.51000E+02 1.58E-01 33 7 3p3/2 4 1.45000E+02 1.58E-01 33 8 3d3/2 4 4.60000E+01 1.23E-01 33 9 3d5/2 6 4.50000E+01 1.23E-01 33 10 4s1/2 2 1.70000E+01 9.22E-01 33 11 4p1/2 -2 9.81000E+00 6.74E-01 33 12 4p3/2 -1 9.81000E+00 6.74E-01 34 1 1s1/2 2 1.26620E+04 2.55E-02 34 2 2s1/2 2 1.65600E+03 9.39E-02 34 3 2p1/2 2 1.47900E+03 4.75E-02 34 4 2p3/2 4 1.43900E+03 4.75E-02 34 5 3s1/2 2 2.34000E+02 2.47E-01 34 6 3p1/2 2 1.73000E+02 1.51E-01 34 7 3p3/2 4 1.66000E+02 1.51E-01 34 8 3d3/2 4 6.10000E+01 1.14E-01 34 9 3d5/2 6 6.00000E+01 1.14E-01 34 10 4s1/2 2 2.01500E+01 8.39E-01 34 11 4p1/2 -2 9.75000E+00 6.04E-01 34 12 4p3/2 -2 9.75000E+00 6.04E-01 35 1 1s1/2 2 1.34810E+04 2.48E-02 35 2 2s1/2 2 1.78700E+03 9.09E-02 35 3 2p1/2 2 1.60200E+03 4.59E-02 35 4 2p3/2 4 1.55600E+03 4.59E-02 35 5 3s1/2 2 2.62000E+02 2.36E-01 35 6 3p1/2 2 1.97000E+02 1.44E-01 35 7 3p3/2 4 1.89000E+02 1.44E-01 35 8 3d3/2 4 7.70000E+01 1.07E-01 35 9 3d5/2 6 7.60000E+01 1.07E-01 35 10 4s1/2 2 2.38000E+01 7.72E-01 35 11 4p1/2 2 1.18500E+01 5.49E-01 35 12 4p3/2 3 1.18500E+01 5.49E-01 36 1 1s1/2 2 1.43270E+04 2.34E-02 36 2 2s1/2 2 1.92460E+03 8.62E-02 36 3 2p1/2 2 1.73090E+03 4.33E-02 36 4 2p3/2 4 1.67840E+03 4.43E-02 36 5 3s1/2 2 2.92800E+02 2.22E-01 36 6 3p1/2 2 2.22200E+02 1.34E-01 36 7 3p3/2 4 2.14400E+02 1.37E-01 36 8 3d3/2 4 9.50000E+01 1.01E-01 36 9 3d5/2 6 9.38000E+01 1.01E-01 36 10 4s1/2 2 2.75100E+01 7.05E-01 36 11 4p1/2 2 1.46500E+01 4.96E-01 36 12 4p3/2 4 1.40000E+01 5.08E-01 37 1 1s1/2 2 1.52030E+04 2.27E-02 37 2 2s1/2 2 2.06800E+03 8.35E-02 37 3 2p1/2 2 1.86700E+03 4.19E-02 37 4 2p3/2 4 1.80700E+03 4.29E-02 37 5 3s1/2 2 3.25000E+02 2.13E-01 37 6 3p1/2 2 2.51000E+02 1.29E-01 37 7 3p3/2 4 2.42000E+02 1.31E-01 37 8 3d3/2 4 1.16000E+02 9.50E-02 37 9 3d5/2 6 1.14000E+02 9.57E-02 37 10 4s1/2 2 3.20000E+01 6.31E-01 37 11 4p1/2 2 1.60000E+01 4.33E-01 37 12 4p3/2 4 1.53000E+01 4.43E-01 37 17 5s1/2 -1 4.18000E+00 2.56E+00 38 1 1s1/2 2 1.61080E+04 2.21E-02 38 2 2s1/2 2 2.21900E+03 8.09E-02 38 3 2p1/2 2 2.01000E+03 4.06E-02 38 4 2p3/2 4 1.94300E+03 4.16E-02 38 5 3s1/2 2 3.61000E+02 2.04E-01 38 6 3p1/2 2 2.83000E+02 1.23E-01 38 7 3p3/2 4 2.73000E+02 1.25E-01 38 8 3d3/2 4 1.39000E+02 9.01E-02 38 9 3d5/2 6 1.37000E+02 9.07E-02 38 10 4s1/2 2 4.00000E+01 5.73E-01 38 11 4p1/2 2 2.30000E+01 3.89E-01 38 12 4p3/2 4 2.20000E+01 3.97E-01 38 17 5s1/2 -2 5.69000E+00 2.06E+00 39 1 1s1/2 2 1.70410E+04 2.15E-02 39 2 2s1/2 2 2.37500E+03 7.85E-02 39 3 2p1/2 2 2.15800E+03 3.94E-02 39 4 2p3/2 4 2.08300E+03 4.04E-02 39 5 3s1/2 2 3.97000E+02 1.96E-01 39 6 3p1/2 2 3.15000E+02 1.18E-01 39 7 3p3/2 4 3.04000E+02 1.20E-01 39 8 3d3/2 4 1.63000E+02 8.56E-02 39 9 3d5/2 6 1.61000E+02 8.63E-02 39 10 4s1/2 2 4.80000E+01 5.33E-01 39 11 4p1/2 2 3.00000E+01 3.61E-01 39 12 4p3/2 4 2.90000E+01 3.66E-01 39 13 4d3/2 -1 6.45000E+00 4.54E-01 39 17 5s1/2 -2 6.45000E+00 1.90E+00 40 1 1s1/2 2 1.80020E+04 2.09E-02 40 2 2s1/2 2 2.53600E+03 7.62E-02 40 3 2p1/2 2 2.31100E+03 3.82E-02 40 4 2p3/2 4 2.22700E+03 3.92E-02 40 5 3s1/2 2 4.34000E+02 1.89E-01 40 6 3p1/2 2 3.48000E+02 1.14E-01 40 7 3p3/2 4 3.35000E+02 1.16E-01 40 8 3d3/2 4 1.87000E+02 8.16E-02 40 9 3d5/2 6 1.85000E+02 8.23E-02 40 10 4s1/2 2 5.60000E+01 5.01E-01 40 11 4p1/2 2 3.50000E+01 3.39E-01 40 12 4p3/2 4 3.30000E+01 3.42E-01 40 13 4d3/2 -2 7.72500E+00 3.93E-01 40 17 5s1/2 -2 7.72500E+00 1.80E+00 41 1 1s1/2 2 1.89900E+04 2.03E-02 41 2 2s1/2 2 2.70200E+03 7.41E-02 41 3 2p1/2 2 2.46900E+03 3.71E-02 41 4 2p3/2 4 2.37500E+03 3.81E-02 41 5 3s1/2 2 4.72000E+02 1.82E-01 41 6 3p1/2 2 3.82000E+02 1.09E-01 41 7 3p3/2 4 3.67000E+02 1.12E-01 41 8 3d3/2 4 2.12000E+02 7.79E-02 41 9 3d5/2 6 2.09000E+02 7.87E-02 41 10 4s1/2 2 6.20000E+01 4.80E-01 41 11 4p1/2 2 4.00000E+01 3.24E-01 41 12 4p3/2 4 3.80000E+01 3.26E-01 41 13 4d3/2 2 7.17000E+00 3.85E-01 41 17 5s1/2 -3 7.07300E+00 1.88E+00 42 1 1s1/2 2 2.00060E+04 1.98E-02 42 2 2s1/2 2 2.87200E+03 7.20E-02 42 3 2p1/2 2 2.63200E+03 3.60E-02 42 4 2p3/2 4 2.52700E+03 3.71E-02 42 5 3s1/2 2 5.11000E+02 1.76E-01 42 6 3p1/2 2 4.16000E+02 1.05E-01 42 7 3p3/2 4 3.99000E+02 1.08E-01 42 8 3d3/2 4 2.37000E+02 7.47E-02 42 9 3d5/2 6 2.34000E+02 7.54E-02 42 10 4s1/2 2 6.80000E+01 4.56E-01 42 11 4p1/2 2 4.50000E+01 3.06E-01 42 12 4p3/2 4 4.20000E+01 3.09E-01 42 13 4d3/2 -4 8.31700E+00 3.47E-01 42 14 4d5/2 -1 8.31700E+00 3.57E-01 42 17 5s1/2 -1 8.31700E+00 1.82E+00 43 1 1s1/2 2 2.10500E+04 1.93E-02 43 2 2s1/2 2 3.04800E+03 7.00E-02 43 3 2p1/2 2 2.80000E+03 3.50E-02 43 4 2p3/2 4 2.68300E+03 3.61E-02 43 5 3s1/2 2 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